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В. І. Штомпель, В. О. Віленський, В. Л. Демченко, Ю. Ю.Керча, С. В. Рябов
«Структура та властивості полімерних композитів на основі епоксидного полімера, поліаніліну та оксиду металу Аl(III) або Fe(III)»
543–551 (2012)

PACS numbers: 61.05.cf, 61.41.+e, 62.23.Pq, 64.60.al, 72.80.Tm, 82.35.Np, 83.80.Ab

The structure and thermal properties of composites based on epoxide resin and mixtures of polyaniline (PAn) and metal oxides (Al2O3 or Fe2O3) are investigated. The dependence of the processes of structure formation in the composites on the type of metal atoms in oxides is revealed. As shown, the impact of PAn on the microheterogeneous structure of the composites with Al2O3 is absent, and for those with Fe2O3, reduction in the effective size of heterogeneity microareas of the composites, lp, more than twice takes place. Smaller segmental mobility, Tc, in the composites with mixture (PAn, Al2O3) as compared to composites with mixture of (PAn, Fe2O3) is revealed.