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B. V. Borts, V. I. Tkachenko, A. V. Moskvitin, and Yu. G. Kazarinov
«Obtaining and Spectrophotometric Study of Organic Solutions of C60 Endo- and Exometallofullerenes
PACS numbers: 07.60.Dq, 61.72.up, 68.49.Sf, 78.40.Ri, 81.05.ub, 81.07.Nb, 81.15.Cd
The method of ion-implantation synthesis of endo- and exofullerenes is developed. The samples of fullerenes containing iron, platinum or their mixture are prepared. Spectrophotometric investigations of low-concentration solutions of metallofullerenes dissolved in organic solvents (toluene) are carried out. As shown, the bonding of metal atoms to the fullerene leads to the broadening of the absorption-spectrum line width and to the absorption-maximum shift to the long-wave part of the spectrum. The half-width and the shift are increasing in the series of С60–С60 ? Pt–С60 ? Fe–С60 ? Fe ? Pt.