Collection of scientific works Nanosystems, nanomaterials, nanotechnologies Year 2024 Volume 22, Issue 2
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MAHMOUD ALSALEH and IBRAHEEM ASAAD ISMAEEL

Preparation of MFe2O4 (M = Ca, Mg) Nanoparticles by Sol–Gel Method and Studying of Their Catalytic Activity
323–334 (2024)

PACS numbers: 61.05.cp, 78.30.Hv, 78.40.Ha, 81.07.Nb, 81.16.Hc, 81.20.Fw, 81.70.Pg

In this paper, MFe2O4 nanoparticles (M = Ca, Mg) are synthesized by sol–gel method using different stabilizer (acetic acid, pectin and beta-carrageenan). The stability of the formed gel is studied extensively by determining the affective conditions (type of stabilizer, molar ratio of stabiliser:M(OH)2:Fe(OH)3, time, and temperature) on the preparation process. The most stabilized gel obtained using beta-carrageenan for both Ca, Mg with (1.2•10-2:1:2), (1.37•10-2:1:2) molar ratios, respectively, during 72 h at 25C. The obtained gel is calcinated and analysed using DTA, XRD and IR spectroscopy. The results show that the calcium ferrite is formed at 493.2C by orthorhombic lattice cell with particle size of 13.01 nm and the magnesium ferrite is formed at 621.4C by cubic crystal phase with particle size of 15.93 nm

KEY WORDS: sol–gel method, beta-carrageenan, calcium ferrite, magnesium ferrite

DOI:  https://doi.org/10.15407/nnn.22.02.323

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