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V.V. TYTARENKO, V.A. ZABLUDOVSKY, and I.V. TYTARENKO

Laser-Assisted Electrodeposition of Composite Carbon-Containing Nickel Coatings
41–52 (2024)

PACS numbers: 62.23.Pq, 68.37.Hk, 68.55.J-, 81.05.uj, 81.15.Pq, 81.16.Mk, 81.65.Kn

The paper presents the study of the structure, protective and mechanical properties of nickel composite coatings modified with ultradispersed diamonds and electrodeposited under conditions of external stimulation by laser radiation. An analysis of the cathodic polarization curves shows that the presence of dispersed particles with a concentration of 2-15 g/l in the aqueous electrolyte solution leads to a shift in the cathodic potential to the electronegative region by 108-340 mV, respectively, that indicates an increase in charge-transfer resistance. Nickel composite coatings obtained by laser-assisted electrodeposition are characterized by a higher content of ultradispersed diamond particles in the coating (4.35-5.10 wt.%) as compared to the mode of deposition without laser irradiation (2.24-3.15 wt.%). In this case, the proportion of particles of smaller size (~0.25-1 µm) increases in the coatings. The more intense penetration of dispersed-phase particles into the emerging coating during the laser stimulation of the electrodeposition process is due to the presence of a temperature gradient, which provides an additional supply of metal ions in the irradiation region. Increased concentration of the dispersed phase in nickel composite coatings promotes formation of a finer crystalline coating structure, enhanced hardness, corrosion resistance, and wear resistance of the coatings.

KEY WORDS: ultradispersed diamond particles, composite nickel coatings, laser-assisted electrodeposition, structure, mechanical and protective properties

DOI:  https://doi.org/10.15407/nnn.22.01.041

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