Collection of scientific works Nanosystems, nanomaterials, nanotechnologies Year 2023 Volume 21, Issue 4
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Araa Hassan Hadi and Majeed Ali Habeeb
Influence of Cobalt Oxide/Zirconium Dioxide Nanoparticles on the Structural and Electrical Behaviour of PVA for Electronic Applications
779–789 (2023)

PACS numbers: 77.22.Ch, 77.22.Gm, 78.20.Ci, 78.30.Jw, 78.67.Sc, 82.35.Np, 85.60.Dw

In this work, we study the effect of cobalt oxide and zirconium dioxide nanoparticles on polyvinyl alcohol with different weight percentages (0, 1, 2, 3 wt.%). Samples are prepared by using solution-casting method. The structural and dielectric characteristics of PVA–CoO–ZrO2 nanocomposites are investigated. Optical microscope images show that the additive distribution of nanoparticles in the blend is homogeneous, and CoO–ZrO2 nanoparticles form a continuous network inside the polymer, when the concentration reached 3 wt.%. Fourier-transform infrared-spectroscopy spectra show a shift in some bands and a change in the intensities; this indicates the considerable not chemical interaction between the polymer and CoO–ZrO2 nanoparticles. The experimental results show that the dielectric constant and dielectric loss of PVA–CoO–ZrO2 nanocomposites are increasing with the increase of cobalt oxide and zirconium oxide nanoparticles’ concentration and are decreasing with the increase of frequency of the applied electric field; on the other hand, the A.C. electrical conductivity is increasing with the increase of frequency and concentration of nanoparticles. Finally, these results show that the PVA–CoO–ZrO2 nanostructures may be useful in different nanoelectronic devices.

Key words: nanocomposites, cobalt oxide, zirconium oxide, FTIR, dielectric properties.

Issue DOI:  https://doi.org/10.15407/nnn.21.04.779

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