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V. A. PROKOPENKO, S. V. NETREBA, O. A. TSYGANOVICH, A. V. PANKO, and I. O. AGEYENKO
Colloid-Chemical Mechanisms of the Formation of Ultra- and Nanosize Iron Oxide/Hydroxide Phases Obtained in the Fe0(St3)–H2O–O2 System and Their Electrokinetic Properties. I. Preparation and Formation Mechanisms of Ultradisperse Phases of [Fe(II)–Fe(III)] LDH, Magnetite, Cobalt-Ferrous Ferrite, Lepidocrocite, and Goethite in the Fe0(St3)–H2O–O2 System
739–756 (2023)

PACS numbers: 64.70.Nd, 68.55.Nq, 75.50.Gg, 75.50.Tt, 81.07.-b, 81.16.Be, 82.70.Dd

In our previous works, the investigation of processes of obtaining and identifying dispersed phases formed in the Fe0(St3)–H2O–O2 system is carried out. At the same time, the analysis of the obtained scientific materials indicates the need for a more thorough study of these processes, taking into account both the analytical conclusions obtained previously and the new data collected during the implementation of this study. The results of this research are summarized in three logically connected articles. The first of them is presented here. This article summarizes the kinetic regularities of formation of the phases of ultradispersed iron–oxygen-containing compounds (UIOCs) in the Fe0(St3)–H2O–O2 system, depending on the physicochemical conditions of the process, and the mechanisms of their formation. It analyses the contribution to the phase formation of various factors, including a steel (St3) disk as an element of an experimental device modelling iron oxidation/reduction processes, electrode processes on its surface, the access of oxygen and carbon dioxide of the air, nanochemical transformations on the surface of the steel disc (SD), and the cationic and anionic compositions of the experimental solution. The results show that the structural elements of steel can contribute to nanochemical transformations, and they can become a source of carbon dioxide and ferrous hydroxide, which participate in the formation of primary UIOCs on the SD surface. The oxidation and transformation of iron layered double hydroxides (LDHs) ([Fe(II)–Fe(III)] LDHs) by the contact-recrystallization mechanism, and the dissolution–reprecipitation or topotactic transformation mechanisms are the main ways of formation of the final ultradispersed and nanoscale phases of magnetite, cobalt-ferrous ferrite, lepidocrocite, and goethite. The article highlights the role of anionic composition in the processes of formation of two [Fe(II)–Fe(III)] LDHs’ types: GRI(ÑÎ32-) and GRII(SO42-). The determining role of electrode processes in the formation of UIOCs is shown. Based on the analysis, the physicochemical conditions for obtaining ultradispersed and nanosize particles of magnetite, cobalt-ferrous ferrite, and lepidocrocite are determined, and the colloidal-chemical properties of the obtained particles are investigated. The methods of x-ray diffraction analysis (XRD), x-ray diffraction in situ (XRD in situ), scanning electron microscopy (SEM), and M?ssbauer spectroscopy are used.

Key words: ultradispersed iron–oxygen-containing compounds (UIOCs), iron(III)-hydroxide oxides, carbon dioxide, iron layered double hydroxides, GRI(CO32-), GRII(SO42-), magnetite, cobalt-ferrous ferrite, lepidocrocite, goethite.

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