Collection of scientific works Nanosystems, nanomaterials, nanotechnologies Year 2023 Volume 21, Issue 3
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Majeed Ali Habeeb, Ahmed Hashim, and Ranya Mahmood Mohammed
Synthesis and Improved Optical Characteristics of Biopolymer Blend Doped with Iron-Oxide Nanoparticles for Optics and Biomedical Applications
617–630 (2023)

PACS numbers: 78.20.Ci,78.40.Me,78.67.Sc,82.35.Lr,82.35.Np,87.19.xb,87.85.Rs

The current study is focused on the enhancement of the optical characteristics of polyethylene-oxide and polyvinyl-alcohol blend with different weight percentages of iron-oxide nanoparticles (0, 1.5%, 3%, 4.5%, and 6% wt.) created by casting technique. Optical examinations show that the absorbance of PEO/PVA/Fe2O3 nanocomposites increases with increase of iron-oxide nanoparticles’ content, while the energy gap of PEO/PVA/Fe2O3 nanocomposites is dropped from 3.79 eV to 3.38 eV and from 2.79 eV to 2.18 eV for allowed and forbidden indirect transitions, respectively, when the addition of iron-oxide nanoparticles reaches 6 wt.%. This feature can play a vital role in enabling PEO/PVA/Fe2O3 nanocomposites for future optoelectronics applications. The refractive index, extinction coefficient, dielectric constant and optical conductivity increase with increasing the concentration of iron-oxide nanoparticles. The antibacterial properties of the PEO/PVA/Fe2O3 nanocomposites are investigated against E. coli bacteria. Experimental results show that the inhibition zone diameter increases with increase of iron-oxide nanoparticles’ concentration. Finally, PEO/PVA/Fe2O3 nanocomposites have a good antibacterial activity.

Key words: bionanocomposites, iron-oxide nanoparticles, optical properties, antibacterial activity.

https://doi.org/10.15407/nnn.21.03.617

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