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2023

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vol. 21 / 

Issue 3

 



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Majeed Ali HABEEB, Ahmed HASHIM, and Ranya Mahmood MOHAMMED
Preparation and Investigation of Structural and Dielectric Properties of PEO–PVA–Fe2O3 Nanocomposites for Electronic Nanodevices
513–525 (2023)

PACS numbers: 77.22.Ch,77.22.Gm,77.55.dj,77.84.Lf,81.05.Qk,81.07.Pr,82.35.Np

The PEO–PVA–Fe2O3 nanocomposites are prepared from mixing PVA and PEO with different concentrations of Fe2O3 nanoparticles (0, 1.5, 3, 4.5 and 6 wt.%) by using the casting method. The structural and dielectric properties of PEO–PVA–Fe2O3 nanocomposites are studied. Optical microscopy images show that the iron-oxide nanoparticles form a continuous network inside the polymer blend at concentration of 4.5 and 6 wt.%. FTIR spectra show shift in some peak position and change in the intensities of others comparing with PEO–PVA blend. The dielectric properties of nanocomposites demonstrate that the dielectric constant, dielectric loss and A.C. electrical conductivity of PEO–PVA blend increase with increasing of Fe2O3 nanoparticles’ concentration. The dielectric constant and dielectric loss of PEO–PVA–Fe2O3 nanocomposites decrease, while the A.C. electrical conductivity increases with increasing frequency. These results indicate that the PEO–PVA–Fe2O3 nanocomposites may be considered as promising materials for electronics and electrical nanodevices.

Key words: polyethylene oxide, polyvinyl alcohol, Fe2O3 nanoparticles, nanocomposites, structural properties, dielectric properties.

https://doi.org/10.15407/nnn.21.03.513

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