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Ahmad Al-Hamdan, Ola Amer, Ahmad Al-Falah, Ibrahim Al-Ghoraibi, Fawaz Al-Deri, and Mirna Jabboure
Synthesis and Characterization of Polypyrrole by Ammonium Persulfate as Oxidizing Agent and Study of Its Nanoparticles
0799–0808 (2022)

PACS numbers: 68.37.Hk, 78.30.Jw, 78.67.Bf, 81.07.Nb, 81.16.Be, 82.35.-x, 82.80.Ej

In this work, pyrrole is polymerized by ammonium persulfate as oxidizing agent in methanol 40%. Pyrrole polymer is characterized by FTIR, XPS and EDX to determine the polymer structure. Morphology of resulting polymer is studied by SEM. Polymer structure consists of spherical particles with sizes of about 38 nm assembled together to form huge clusters. Pyrrole polymer has semi-crystalline structure; its particles consist of crystalline core with size of 15.1 nm, surrounded by an amorphous shell fraction. Particles’ size by XRD data is of 35.59 nm. This size may be more accurate than SEM size as XRD sample includes larger number of particles than SEM sample.

Key words: polymerization, pyrrole polymer, nanoparticles, semi-crystalline structure, XRD.

https://doi.org/10.15407/nnn.20.03.799

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