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А. С. Безкровный, Ю. В. Ермолаева, Н. А. Матвеевская, Н. А. Дулина, О. М. Вовк, Н. И. Даниленко, А. В. Толмачев
«Кристаллизация нанопорошков (Y1-xEux)2O3 со сферической морфологией в условиях ограниченной размерности»
355–364 (2014)

PACS numbers: 61.05.cp, 61.46.Df, 64.60.qj, 65.80.+n, 68.37.Lp, 81.07.Wx, 81.10.Jt

Polycrystalline spherical-shape particles of substitutional solid solutions (Y1-xEux)2O3 (x = 00.09) are obtained by low-temperature thermolysis and crystallization of amorphous precursor (Т = 6001000°!). The main structural and morphological parameters, such as polycrystalline structure, mesoporosity, controllability of their diameters in 100–300 nm range with dispersion lower than 15%, are determined. As shown, the Eu3+ activator doping influences on the final diameters of the spheres with formation of (Y1-xEux)2O3 solid solution. Optimal temperature conditions of spheres’ crystallization with resulting equilibrium diameter and with crystallites’ size of 40–47 nm are determined.