Выпуски

 / 

2013

 / 

том 11 / 

выпуск 1

 



Скачать полную версию статьи (в PDF формате)

Н. С. Аникина, Д. В. Щур, С. Ю. Загинайченко, О. Я. Кривущенко, М. А. Полищук, Л. Л. ЧимбайН. С. Аникина, Д. В. Щур, С. Ю. Загинайченко, О. Я. Кривущенко, М. А. Полищук, Л. Л. Чимбай
«Закономерности растворения фуллерена С60 в полиметилзамещённых бензола»
0173–0192 (2013)

PACS numbers: 64.75.Bc, 82.30.Vy, 82.35.Np, 82.45.Wx, 82.80.Fk

The process of fullerene С60 dissolution in polymethyl-substituted benzenes is considered as a reaction of intermolecular ?-donor–acceptor interaction leading to the formation of charge-transfer complexes of ?-type that allows revealing the regularity of dissolution of fullerene С60 in polymethylbenzenes. The ?-electron-acceptor ‘effect of –СН3 group in the meta-position’ of the aromatic ring is revealed. The method for calculation of the С60 fullerene solubility in polymethyl-substituted benzenes is developed. As ascertained, the change in the solubility of С60 in polymethylbenzenes at the ‘introduction’ (or ‘breeding’) of the СН3-groups in the benzene nucleus does not depend on the already existing number and arrangement of the СН3-groups in polymethyl-benzene. An explanation for the low solubility of fullerene С60 in organic solvents is presented.

©2003—2019 NANOSISTEMI, NANOMATERIALI, NANOTEHNOLOGII G. V. Kurdyumov Institute for Metal Physics of the National Academy of Sciences of Ukraine.
E-mail: tatar@imp.kiev.ua Phones and address of the editorial office About the collection User agreement