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Н. С. Аникина, Д. В. Щур, С. Ю. Загинайченко, О. Я. Кривущенко, М. А. Полищук, Л. Л. ЧимбайН. С. Аникина, Д. В. Щур, С. Ю. Загинайченко, О. Я. Кривущенко, М. А. Полищук, Л. Л. Чимбай
«Закономерности растворения фуллерена C60 в полиметилзамещённых бензола»
173–192 (2013)

PACS numbers: 64.75.Bc, 82.30.Vy, 82.35.Np, 82.45.Wx, 82.80.Fk

The process of fullerene C60 dissolution in polymethyl-substituted benzenes is considered as a reaction of intermolecular ?-donor–acceptor interaction leading to the formation of charge-transfer complexes of ?-type that allows revealing the regularity of dissolution of fullerene C60 in polymethylbenzenes. The ?-electron-acceptor ‘effect of –СН3 group in the meta-position’ of the aromatic ring is revealed. The method for calculation of the C60 fullerene solubility in polymethyl-substituted benzenes is developed. As ascertained, the change in the solubility of C60 in polymethylbenzenes at the ‘introduction’ (or ‘breeding’) of the СН3-groups in the benzene nucleus does not depend on the already existing number and arrangement of the СН3-groups in polymethyl-benzene. An explanation for the low solubility of fullerene C60 in organic solvents is presented.