Collection of scientific works Nanosystems, nanomaterials, nanotechnologies
Year 2026 Volume 24, Issue 2
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V. V. TRACHEVSKY

Technical Centre, N.A.S. of Ukraine, 13, Pokrovska Str., UA-04070 Kyiv, Ukraine

EPR Diagnostics of Self-Organization in Mo(V)-Containing Systems

361–408 (2026)

PACS numbers: 05.65.+b, 33.35.+r, 61.72.Hh, 71.70.Ch, 76.30.-v, 87.64.kh, 87.80.Lg

Received 25 December, 2025; in revised form, 7 May, 2026

It is carried out a systematic analysis of the EPR-data array for molybdenum(V) located in condensed media in forms, which differ by the nature of the donor environment (F, Cl, Br, I, O, S, Se, N, P), local co-ordination numbers (from 4 to 8) and the symmetry of the co-ordination sphere polyhedra (tetrahedron, trigonal bipyramid, tetragonal pyramid, distorted octahedron, trigonal prism, pentagonal bipyramid, dodecahedron), the nature of the structure-determining atom of the functional groups of reagents (C, S, P, As, etc.) with different combinations of donor atoms in the chelate cycle of varying complexity, the presence of multiple-bonded ligands (=O, =N−R, =N−NR2, ≡N, =P−R, =S, =Se, and among them, for the first time organized multiple-bonded chelating ones), the possibility of forming heteronuclear clusters with Nb(V), Cu(II) and mixed-ligand compounds, the nature of interligand innersphere interactions (hydrogen bonding, stacking effect, and noncovalent S...S, Se...Se, Br...Br, I...I contacts).

KEY WORDS: EPR-spectra parameters, synergetic self-organization, mono-, bi- and multiple-bonded ligands, co-ordination sphere configuration

DOI: https://doi.org/10.15407/nnn.24.02.0361

Citation:
V. V. Trachevsky, EPR Diagnostics of Self-Organization in Mo(V)-Containing Systems, Nanosistemi, Nanomateriali, Nanotehnologii, 24, No. 2: 361–408 (2026); https://doi.org/10.15407/nnn.24.02.0361

Funding / Acknowledgments:
The author confirms that the conceptualization, literature review and analysis, collection of experimental data, and writing of the manuscript were carried out by him personally.
The work was carried out and funded within the framework of the research project ‘Synthesis, Structure and Properties of Ligand-Stabilized Nanoclusters — Superatoms’ (state registration No. 0120U100074).
The author declares no conflict of interest.

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