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1College of Education for Pure Sciences, Department of Physics, University of Babylon, Hillah, Iraq
2College of Engineering, Department of Mechanical Engineering, Wasit University, Wasit, Iraq

Structural and Optical Characteristics of PVA/SnO2/MnO2 Nanocomposites for Optical Devices

1171–1181 (2025)

PACS numbers: 68.55.J-, 78.20.Ci, 78.30.-j, 78.40.-q, 78.67.Sc, 81.40.Tv, 82.35.Np

In this research, different concentrations of manganese dioxide (MnO2) and tin dioxide (SnO2) are composed with polyvinyl alcohol (PVA) to form the PVA/MnO2/SnO2 films. The optical images demonstrate surface structure and morphological characteristics of the prepared films. The FTIR of PVA/SnO2/MnO2 nanocomposites manifest the obvious broad peaks at 3264 and 3242 cm−1 due to –OH groups and at 2020 cm−1 due to stretching vibrations. The optical characteristics of PVA/MnO2/SnO2 films are recorded by means of UV–Vis spectroscopy. The band gap is reduced from 3.73 eV to 2.95 eV for PVA/SnO2/MnO2 nanocomposites, and the absorbance is increased with the increasing of SnO2/MnO2 added to PVA. The optical conductivity also is increased with the increasing of incident photon energy. These results open a good opportunity for applications in different devices such as energy storage systems and optoelectronics devices.

KEY WORDS: nanocomposites, structural and optical properties, optical devices

DOI: https://doi.org/10.15407/nnn.23.04.1171

Citation:
Saad Abbas Jasim, M. Jawad K, Olaa H. Altemeemi, Majeed Ali Habeeb, and Halah Mohammed, Structural and Optical Characteristics of PVA/SnO2/MnO2 Nanocomposites for Optical Devices, Nanosistemi, Nanomateriali, Nanotehnologii, 23, No. 4: 1171–1181 (2025); https://doi.org/10.15407/nnn.23.04.1171
REFERENCES
  1. V. M. Mohan, P. B. Bhargav, V. Raja, A. K. Sharma, and V. V. R. Narasimha Rao, Soft Materials, 5, No. 1: 33 (2007); https://doi.org/10.1080/15394450701405291
  2. Shaimaa Mazhar Mahdi and Majeed Ali Habeeb, Optical and Quantum Electronics, 54: Article No. 854 (2022); https://doi.org/10.1007/s11082-022-04267-6
  3. R. Tintu, K. Saurav, K. Sulakshna, V. P. N. Nampoori, P. Radhakrishnan, and S. Thomas, J. Nan. Oxide Glas., 2, No. 4: 167 (2010).
  4. M. A. Habeeb and Z. S. Jaber, East European Journal of Physics, 4: 176 (2022); doi:10.26565/2312-4334-2022-4-18
  5. M. A. Habeeb, European Journal of Scientific Research, 57, No. 3: 478 (2011).
  6. Q. M. Jebur, A. Hashim, and M. A. Habeeb, Egyptian Journal of Chemistry, 63: 719 (2020); https://dx.doi.org/10.21608/ejchem.2019.14847.1900
  7. S. Ganeshan, P. Ramasundari, A. Elangovan, G. Arivazhagan, and R. Vijayalakshmi, Int. J. Sci. Res. Phys. Appl. Sci., 5, No. 6: 5 (2017); https://doi.org/10.26438/ijsrpas/v5i6.58
  8. A. H. Hadi and M. A. Habeeb, Journal of Mechanical Engineering Research and Developments, 44, No. 3: 265 (2021); https://jmerd.net/03-2021-265-274/
  9. N. Hayder, M. A. Habeeb, and A. Hashim, Egyptian Journal of Chemistry, 63: 577 (2020); doi:10.21608/ejchem.2019.14646.1887
  10. Shaimaa Mazhar Mahdi and Majeed Ali Habeeb, Polymer Bulletin, 80, No. 12: 12741 (2023); https://doi.org/10.1007/s00289-023-04676-x
  11. M. A. Habeeb, A. Hashim, and N. Hayder, Egyptian Journal of Chemistry, 63: 709 (2020); https://dx.doi.org/10.21608/ejchem.2019.13333.1832
  12. A. Hashim, M. A. Habeeb, and Q. M. Jebur, Egyptian Journal of Chemistry, 63: 735 (2020); https://dx.doi.org/10.21608/ejchem.2019.14849.1901
  13. S. M. Mahdi and M. A. Habeeb, Physics and Chemistry of Solid State, 23, No. 4: 785 (2022); doi:10.15330/pcss.23.4.785-792
  14. Nawras Karim Al-Sharifi and Majeed Ali Habeeb, Silicon, 15: 4979 (2023); https://doi.org/10.1007/s12633-023-02418-2
  15. Majeed Ali Habeeb and Waleed Shaker Mahdi, International Journal of Emerging Trends in Engineering Research, 7, No. 9: 247 (2019); doi:10.30534/ijeter/2019/06792019
  16. M. A. Habeeb and R. S. Abdul Hamza, Journal of Bionanoscience, 12, No. 3: 328 (2018); https://doi.org/10.1166/jbns.2018.1535
  17. Ahmed Hashim, Alaa J. Kadham Algidsawi, Hind Ahmed, Aseel Hadi, and Majeed Ali Habeeb, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 2: 353 (2021); https://doi.org/10.15407/nnn.19.02.353
  18. M. A. Habeeb, A. Hashim, and N. Hayder, Egyptian Journal of Chemistry, 63: 697 (2020); https://dx.doi.org/10.21608/ejchem.2019.12439.1774
  19. M. A. Habeeb and W. K. Kadhim, Journal of Engineering and Applied Sciences, 9, No. 4: 109 (2014); doi:10.36478/jeasci.2014.109.113
  20. Alaa Abass Mohammed and Majeed Ali Habeeb, Silicon, 15: 5163 (2023); https://doi.org/10.1007/s12633-023-02426-2
  21. M. A. Habeeb, Journal of Engineering and Applied Sciences, 9, No. 4: 102 (2014); doi:10.36478/jeasci.2014.102.108
  22. Ahmed Hashim, Alaa J. Kadham, Aseel Hadi, and Majeed Ali Habeeb, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 2: 327 (2021); https://doi.org/10.15407/nnn.19.02.327
  23. S. M. Mahdi and M. A. Habeeb, Digest Journal of Nanomaterials and Biostructures, 17, No. 3: 941 (2022); https://doi.org/10.15251/DJNB.2022.173.941
  24. Ahmed Hashim, Alaa J. Kadham Algidsawi, Hind Ahmed, Aseel Hadi, and Majeed Ali Habeeb, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 1: 91 (2021); https://doi.org/10.15407/nnn.19.01.091
  25. Araa Hassan Hadi and Majeed Ali Habeeb, Journal of Physics: Conference Series, 1973, No. 1: 012063 (2021); doi:10.1088/1742-6596/1973/1/012063
  26. Q. M. Jebur, A. Hashim, and M. A. Habeeb, Egyptian Journal of Chemistry, 63, No. 2: 611 (2020); https://dx.doi.org/10.21608/ejchem.2019.10197.1669
  27. C. Uma Devi, A. K. Sharma, and V. V. R. N. Rao, Materials Letters, 56, No. 3: 167 (2002); https://doi.org/10.1016/S0167-577X(02)00434-2
  28. Majeed Ali Habeeb and Ahmed Hashim Mohammed, Optical and Quantum Electronics, 55: Article No. 791 (2023); https://doi.org/10.1007/s11082-023-05061-8
  29. M. H. Dwech, M. A. Habeeb, and A. H. Mohammed, Ukr. J. Phys., 67, No. 10: 757 (2022); https://doi.org/10.15407/ujpe67.10.757
  30. Rehab Shather Abdul Hamza and Majeed Ali Habeeb, Optical and Quantum Electronics, 55: Article No. 705 (2023); https://doi.org/10.1007/s11082-023-04995-3
  31. Alaa J. Kadham Algidsawi, Ahmed Hashim, Aseel Hadi, Majeed Ali Habeeb, and Hussein Hakim Abed, Physics and Chemistry of Solid State, 23, No. 2: 353 (2022); https://doi.org/10.15330/pcss.23.2.353-360
  32. Majeed Ali Habeeb and Waleed Hadi Rahdi, Optical and Quantum Electronics, 55: Article No. 334 (2023); https://doi.org/10.1007/s11082-023-04639-6
  33. H. N. Chandrakala, B. Ramaraj, Shivakumaraiah, G. M. Madhu, and Siddaramaiah, Journal of Alloys and Compounds, 551: 531 (2013); https://doi.org/10.1016/j.jallcom.2012.10.188
  34. A. Hashim and M. A. Habeeb, Journal of Bionanoscience, 12, No. 5: 660 (2018); https://doi.org/10.1166/jbns.2018.1578
  35. Shaimaa Mazhar Mahdi and Majeed Ali Habeeb, AIMS Materials Science, 10, No. 2: 288 (2023); doi:10.3934/matersci.2023015
  36. J. Selvi, S. S. Mahalakshmi, and V. Parthasarathy, J. Inorg. Organomet. Polym. Mater., 27: 1918 (2017); https://doi.org/10.1007/s10904-017-0662-1
  37. Nawras Karim Al-Sharifi and Majeed Ali Habeeb, East European Journal of Physics, 2: 341 (2023); doi:10.26565/2312-4334-2023-2-40
  38. A. J. K. Algidsawi, A. Hashim, A. Hadi, and M. A. Habeeb, Semiconductor Physics, Quantum Electronics and Optoelectronics, 24, No. 4: 472 (2021); https://doi.org/10.15407/spqeo24.04.472
  39. Nhiem Tran, Aparna Mir, Dhriti Mallik, Arvind Sinha, Suprabha Nayar, and Thomas J Webster, Int. J. Nanomedicine, 5: 277 (2010); https://doi.org/10.2147/IJN.S9220
  40. Zainab Sabry Jaber, Majeed Ali Habeeb, and Waleed Hadi Radi, East European Journal of Physics, 2: 228 (2023); doi:10.26565/2312-4334-2023-2-25
  41. M. A. Habeeb and R. S. A. Hamza, Indonesian Journal of Electrical Engineering and Informatics, 6, No. 4: 428 (2018); doi:10.11591/ijeei.v6i1.511
  42. A. A. Mohammed and M. A. Habeeb, East European Journal of Physics, 2: 157 (2023); doi:10.26565/2312-4334-2023-2-15
  43. O. E. Gouda, S. F. Mahmoud, A. A. El-Gendy, and A. S. Haiba, Indonesian Journal of Electrical Engineering, 12, No. 12: 7987 (2014); https://doi.org/10.11591/telkomnika.v12i12.6675