Collection of scientific works Nanosystems, nanomaterials, nanotechnologies
Year 2025 Volume 23, Issue 4
Download the full version of the article (PDF) Open Access

Ahmed HASHIM1, Hamed IBRAHIM2, Batool MOHAMMED1, Eman Hammod ABDULLAH1, and Aseel HADI3

1College of Education for Pure Sciences, Department of Physics, University of Babylon, Hillah, Iraq
2Al-Zahraa University for Women, Baghdad Road (opposite pole 70), Kerbala, Iraq
3College of Materials Engineering, Department of Ceramic and Building Materials, University of Babylon, Hillah, Iraq

Fabrication and Enhanced Optical Properties of ZrO2/PbO2-Nanostructures-Doped PVA for Optoelectronics Fields

1155–1162 (2025)

PACS numbers: 78.20.Ci, 78.40.-q, 78.67.Sc, 81.07.Pr, 81.40.Tv, 82.35.Np, 85.60.Bt

Received 28 November, 2023

This work aims to fabricate of the PVA–ZrO2–PbO2 nanocomposites and to investigate the optical properties to utilize them in different optical and electronic fields. The optical properties of the PVA–ZrO2–PbO2 nanocomposites are tested in wavelength range 200–800 nm. The results show that the PVA–ZrO2–PbO2 nanocomposites have high absorption in UV region. The PVA absorbance is increased, while both the transmittance and the energy band gap are reduced with increasing ZrO2–PbO2-NPs’ content. The obtained results show that the PVA–ZrO2–PbO2 nanocomposites may be useful in different optoelectronics applications.

KEY WORDS: PVA, PbO2, ZrO2, nanocomposites, absorbance, energy gap

DOI: https://doi.org/10.15407/nnn.23.04.1155

Citation:
Ahmed Hashim, Hamed Ibrahim, Batool Mohammed, Eman Hammod Abdullah, and Aseel Hadi, Fabrication and Enhanced Optical Properties of ZrO2/PbO2-Nanostructures-Doped PVA for Optoelectronics Fields, Nanosistemi, Nanomateriali, Nanotehnologii, 23, No. 4: 1155–1162 (2025); https://doi.org/10.15407/nnn.23.04.1155
REFERENCES
  1. Ali F Al-Shawabkeh, Ziad M Elimat, and Khaleel N Abushgair, J. of Thermoplastic Comp. Mater., 36, Iss. 3: 1 (2021); https://doi.org/10.1177/08927057211038631
  2. R. Ambrosio, A. Carrillo, M. de la L. Mota, K. de la Torre, R. Torrealba, M. Moreno, H. Vazquez, J. Flores, and I. Vivaldo, Polymers, 10, Iss. 12: 1 (2018); doi:10.20944/preprints201810.0567.v1
  3. C. Srikanth, C. Sridhar, B. M. Nagabhushana, and R. D. Mathad, J. of Adv. Phys., 5, Iss. 2: 105 (2014); https://doi.org/10.1166/jap.2016.1235
  4. Chougale Ravindra, Masti Sarswati, Gouda Sukanya, Patil Shivalila, Yakkerimath Soumya, and Kasai Deepak, Research Journal of Physical Sciences, 3, Iss. 8: 1 (2015); https://www.isca.me/PHY_SCI/Archive/v3/i8/1.ISCA-RJPS-2015-014.pdf
  5. H. A. J. Hussien, R. G. Kadhim, and A. Hashim, J. of Physics: Conf. Series, 1818: 1 (2021); doi:10.1088/1742-6596/1818/1/012187
  6. Abeer Ghalib Hadi, Zainab Al-Ramadhan, and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 4: 865 (2021); https://doi.org/10.15407/nnn.19.04.865
  7. Ahmed Hashim and Zinah Sattar Hamad, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 4: 893 (2021); https://doi.org/10.15407/nnn.19.04.893
  8. Hind Ahmed and Ahmed Hashim, International Journal of Scientific & Technology Research, 8, Iss. 11: 1014 (2019); https://www.ijstr.org/final-print/nov2019/Fabrication-Of-Novel-pvaniosic-Nanocomposites-Structural-Electronic-And-Optical-Properties-For-Humidity-Sensors.pdf
  9. Batool Mohammed, Hind Ahmed, and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 20, Iss. 1: 187 (2022); https://doi.org/10.15407/nnn.20.01.187
  10. Huda Abdul Jalil Hussien, Raheem G. Kadhim, and Ahmed Hashim, J. of Physics: Conf. Series, 1818: 012119 (2021); doi:10.1088/1742-6596/1818/1/012119
  11. Huda Abdul Jalil Hussien, Raheem G. Kadhim, and Ahmed Hashim, J. of Physics: Conf. Series, 1818: 012186 (2021); doi:10.1088/1742-6596/1818/1/012186
  12. Huda Bukheet Hassan, Hayder M. Abduljalil, and Ahmed Hashim, AIP Conference Proceedings, 2591: 040008 (2023); https://doi.org/10.1063/5.0119838
  13. Noor Al-Huda Al-Aaraji, Ahmed Hashim, Hayder M. Abduljalil, and Aseel Hadi, Optical and Quantum Electronics, 55: Article No. 743 (2023); https://doi.org/10.1007/s11082-023-05048-5
  14. Huda Bukheet Hassan, Hayder M. Abduljalil, and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 21, Iss. 2: 289 (2023); https://doi.org/10.15407/nnn.21.02.289
  15. Hind Ahmed and Ahmed Hashim, Silicon, 15: 83 (2023); https://doi.org/10.1007/s12633-022-01978-z
  16. F. S. Jaber, A. Hashim, and H. M. Abduljalil, Silicon, 15: 71(2023); https://doi.org/10.1007/s12633-022-02000-2
  17. Hind Ahmed and Ahmed Hashim, Optical and Quantum Electronics, 54: Article No. 403 (2022); https://doi.org/10.1007/s11082-022-03784-8
  18. Hind Ahmed and Ahmed Hashim, Silicon, 14: 4079 (2022); https://doi.org/10.1007/s12633-021-01186-1
  19. Hind Ahmed and Ahmed Hashim, Journal of Molecular Modeling, 26: Article No. 210 (2020); doi:10.1007/s00894-020-04479-1
  20. Hind Ahmed and Ahmed Hashim, Silicon, 14: 4907 (2022); https://doi.org/10.1007/s12633-021-01258-2
  21. Hind Ahmed and Ahmed Hashim, Trans. Electr. Electron. Mater., 23: 237 (2022); https://doi.org/10.1007/s42341-021-00340-1
  22. Hind Ahmed and Ahmed Hashim, Silicon, 14: 7025 (2021); https://doi.org/10.1007/s12633-021-01465-x
  23. Hind Ahmed and Ahmed Hashim, Opt. Quant. Electron., 55: 280 (2023); https://doi.org/10.1007/s11082-022-04528-4
  24. Batool Mohammed, Hind Ahmed, and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 21, Iss. 1: 113 (2023); https://doi.org/10.15407/nnn.21.01.113
  25. Hind Ahmed and Ahmed Hashim, Physics and Chemistry of Solid State, 23, No. 1: 67 (2022); doi:10.15330/pcss.23.1.67-71
  26. Huda Bkheet Hasan, Hayder M. Abduljalil, and Ahmed Hashim, Physics and Chemistry of Solid State, 23, No. 3: 454 (2022); doi:10.15330/pcss.23.3.454-460
  27. Hind Ahmed and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 4: 841 (2021); https://doi.org/10.15407/nnn.19.04.841
  28. Farhan Lafta Rashid, Aseel Hadi, Ammar Ali Abd, and Ahmed Hashim, International Journal of Advances in Applied Sciences, 8, No. 2: 154 (2019); doi:10.11591/ijaas.v8i2.pp154-156
  29. Maithem Hussein Rasheed, Ahmed Hashim, and Farhan Lafta Rashid, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 2: 374 (2021); https://doi.org/10.15407/nnn.19.02.347
  30. Ahmed Hashim, Farhan Lafta Rashid, Noor Al-Huda Al-Aaraji, and Bahaa H. Rabee, East European Journal of Physics, 1: 173 (2023); doi:10.26565/2312-4334-2023-1-21
  31. Farhan Lafta Rashid, Ahmed Hashim, Noor Al-Huda Al-Aaraji, and Aseel Hadi, East European Journal of Physics, 1: 177 (2023); doi:10.26565/2312-4334-2023-1-22
  32. A. S. Shareef, Farhan Lafta Rashid, Aseel Hadi and Ahmed Hashim, International Journal of Scientific & Technology Research, 8, Iss. 11: 1041 (2019).
  33. Aseel Hadi, Ahmed Hashim, and Dalal Hassan, Bulletin of Electrical Engineering and Informatics, 9, No. 1: 83 (2020); doi:10.11591/eei.v9i1.1323
  34. Hind Ahmed and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 20, Iss. 4: 951 (2022); https://doi.org/10.15407/nnn.20.04.951
  35. Farhan Lafta Rashid, Ahmed Hashim, Mohammed H. Abbas, and Aseel Hadi, East European Journal of Physics, 1: 181 (2023); doi:10.26565/2312-4334-2023-1-23
  36. Ahmed Hashim, Farhan Lafta Rashid, Mohammed H. Abbas, and Bahaa H. Rabee, East European Journal of Physics, 1: 185 (2023); doi:10.26565/2312-4334-2023-1-24
  37. A. A. Al-Muntaser, Rami Adel Pashameah, Abdu Saeed, Reem Alwafi, Eman Alzahrani, Samah A. AlSubhi, and A. Y. Yassin, J. Mater. Sci.: Mater. Electron., 34: 1 (2023); https://doi.org/10.1007/s10854-023-10104-7
  38. T. A.-Baset, M. Elzayat, and S. Mahrous, Int. J. of Polym. Sci., 2016: Article ID 1707018 (2016); http://dx.doi.org/10.1155/2016/1707018
  39. Ahmed Hashim, Eman Hammod Abdullah, Farhan Lafta Rashid, and Aseel Hadi, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 3: 697 (2021); https://doi.org/10.15407/nnn.19.03.697
  40. Marwa Sajjad and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 4: 831 (2021); https://doi.org/10.15407/nnn.19.04.831
  41. Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 3: 647 (2021); https://doi.org/10.15407/nnn.19.03.647
  42. Musaab Khudhur Mohammed, Eman Hammod Abdullah, Dalal Hassan, and Ahmed Hashim, Revue des Composites et des Matériaux Avancés—Journal of Composite and Advanced Materials, 32, No. 6: 305 (2022); https://doi.org/10.18280/rcma.320606
  43. Yousif Y. Mijbil and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 20, Iss. 2: 497 (2022); https://doi.org/10.15407/nnn.20.02.497
  44. Maithem Hussein Rasheed, Abdulsattar Khudhair Abbas, Farhan Lafta Rashid, and Ahmed Hashim, Nanosistemi, Nanomateriali, Nanotehnologii, 20, Iss. 3: 761 (2022); https://doi.org/10.15407/nnn.20.03.761
  45. Ahmed Hashim, Aseel Hadi, and M. H. Abbas, Silicon, 15: 6431 (2023); https://doi.org/10.1007/s12633-023-02529-w
  46. Ahmed Hashim, Aseel Hadi, and Noor Al-Huda Al-Aaraji, Optical and Quantum Electronics, 55: Article No. 716 (2023); https://doi.org/10.1007/s11082-023-04994-4
  47. Ahmed Hashim, Batool Mohammed, Aseel Hadi, and Hamed Ibrahim, Journal of Inorganic and Organometallic Polymers and Materials, 34: 611 (2024); https://doi.org/10.1007/s10904-023-02846-y
  48. Huda Bukheet Hassan, Ahmed Hashim, and Hayder M. Abduljalil, Optical and Quantum Electronics, 55: Article No. 556 (2023); https://doi.org/10.1007/s11082-023-04830-9
  49. Hiba Kamil Jaafar, Ahmed Hashim, and Bahaa H. Rabee, Optical and Quantum Electronics, 55: Article No. 989 (2023); https://doi.org/10.1007/s11082-023-05208-7
  50. Ahmed Hashim, Saif M. Alshrefi, Hussein H. Abed, and Aseel Hadi, Journal of Inorganic and Organometallic Polymers and Materials, 34: 703 (2024); https://doi.org/10.1007/s10904-023-02866-8
  51. Ola Basim Fadil and Ahmed Hashim, Silicon, 14: 9845 (2022); https://doi.org/10.1007/s12633-022-01728-1
  52. Wissam Obeis Obaid and Ahmed Hashim, Silicon, 14: 11199 (2022); https://doi.org/10.1007/s12633-022-01854-w
  53. Hiba Kamil Jaafar, Ahmed Hashim, and Bahaa H. Rabee, Silicon, 16: 603 (2024); https://doi.org/10.1007/s12633-023-02706-x
  54. Huda Abdul Jalil Hussien, Raheem G. Kadhim, and Ahmed Hashim, Optical and Quantum Electronics, 54: Article No. 704 (2022); https://doi.org/10.1007/s11082-022-04094-9
  55. Huda Bukheet Hassan, Ahmed Hashim, and Hayder M. Abduljalil, Polymer Bulletin, 80: 9059 (2023); https://doi.org/10.1007/s00289-022-04502-w
  56. Huda Abdul Jalil Hussien, Raheem G. Kadhim, and Ahmed Hashim, Optical and Quantum Electronics, 53: Article No. 501 (2021); https://doi.org/10.1007/s11082-021-03157-7
  57. Huda Abdul Jalil Hussien, Raheem G. Kadhim, and Ahmed Hashim, Polymer Bulletin, 79: 5219 (2022); https://doi.org/10.1007/s00289-021-03778-8
  58. Ahmed Hashim, Opt. Quant. Electron., 53: Article No. 478 (2021); https://doi.org/10.1007/s11082-021-03100-w
  59. Ghaith Ahmed and Ahmed Hashim, Silicon, 15: 7085 (2023); https://doi.org/10.1007/s12633-023-02572-7
  60. Angham Hazim, Ahmed Hashim, and Hayder M. Abduljalil, Egypt. J. Chem., 64, No. 1: 359 (2021); doi:10.21608/EJCHEM.2019.18513.2144
  61. Arshad Fadhil Kadhim and Ahmed Hashim, Opt. Quant. Electron., 55: Article No. 432432 (2023); https://doi.org/10.1007/s11082-023-04699-8
  62. Mohanad H. Meteab, Ahmed Hashim, and Bahaa H. Rabee, Opt. Quant. Electron., 55: Article No. 187 (2023); https://doi.org/10.1007/s11082-022-04447-4
  63. Angham Hazim, Ahmed Hashim, and Hayder M. Abduljalil, Nanosistemi, Nanomateriali, Nanotehnologii, 18, Iss. 4: 983 (2020); https://doi.org/10.15407/nnn.18.04.983
  64. Ahmed Hashim, Zinah Sattar Hamad, Nanosistemi, Nanomateriali, Nanotehnologii, 18, Iss. 4: 969 (2020); https://doi.org/10.15407/nnn.18.04.969
  65. Ahmed Hashim, Aseel Hadi, Hamed Ibrahim, and Farhan Lafta Rashid, Journal of Inorganic and Organometallic Polymers and Materials, 34: 1678 (2024); https://doi.org/10.1007/s10904-023-02908-1