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College of Education for Pure Sciences, Department of Physics, University of Babylon, Hillah, Iraq

Synthesis of Polymer Blend/Ag Nanocomposites: Morphological and Structural Properties for Gamma-Ray Shielding

1137–1145 (2025)

PACS numbers: 78.30.-j, 78.67.Sc, 81.07.Pr, 82.35.Np, 83.80.Tc, 85.60.Bt

In order to use the nanocomposites (NCs) in a variety of optoelectronic nanodevices, this work attempts to create unique nanocomposite films by incorporating silver (Ag) nanostructures into polyvinyl alcohol (PVA) and polyethylene glycol (PEG). When compared with other nanosystems, PVA/PEG–Ag nanostructures have favourable properties: low weight, improved corrosion resistance, and low cost. The purpose of this work is to examine the structural properties of nanostructures made of PVA/PEG–Ag NCs. As suggested, from FTIR spectra, there is a physical contact between the polymer blend and the nanoparticles (NPs), which leads to a physical interaction between the nanocomposites and the polymer. With the optical microscope, it is observed that a continuous network is formed for the nanoparticles inside the polymer. The nanocomposites created are tested to see, if they could block gamma radiation. According to the experimental results, when exposed by gamma rays, the nanocomposite films of PVA–PEG/Ag NCs exhibit remarkable attenuation coefficients. Thus, it is clear that the addition of Ag NPs improves the final nanocomposite, and this material is believed to be a promising material for gamma-ray shielding and flexible optoelectronic applications.

KEY WORDS: PVA/PEG–Ag nanostructures, FTIR spectra, attenuation coefficient

DOI: https://doi.org/10.15407/nnn.23.04.1137

Citation:
Majeed Ali Habeeb and Shaimaa Mazhar Mahdi, Synthesis of Polymer Blend/Ag Nanocomposites: Morphological and Structural Properties for Gamma-Ray Shielding, Nanosistemi, Nanomateriali, Nanotehnologii, 23, No. 4: 1137–1145 (2025); https://doi.org/10.15407/nnn.23.04.1137
REFERENCES
  1. Flávio James Tommasinia, Leonardo da Cunha Ferreira, Lucas Galhardo Pimenta Tienneb, Vinícius de Oliveira Aguiar, Marcelo Henrique Prado da Silvaa, Luiz Felipe da Mota Rochab, and Maria de Fátima Vieira Marques, Materials Research, 21, No. 6: 523 (2018); https://doi.org/10.1590/1980-5373-MR-2018-0086
  2. Q. M. Jebur, A. Hashim, and M. A. Habeeb, Egyptian Journal of Chemistry, 63: 719 (2020); https://doi.org/10.21608/ejchem.2019.14847.1900
  3. V. M. Mohan, P. B. Bhargav, V. Raja, A. K. Sharma, and V. V. R. Narasimha Rao, Soft Mater., 5, No. 1: 33 (2007); https://doi.org/10.1080/15394450701405291
  4. M. A. Habeeb and Z. S. Jaber, East European Journal of Physics, 4: 176 (2022); https://doi.org/10.26565/2312-4334-2022-4-18
  5. M. A. Habeeb, European Journal of Scientific Research, 57, No. 3: 478 (2011).
  6. S. M. Mahdi and M. A. Habeeb, Optical and Quantum Electronics, 54, Iss. 12: 854 (2022); https://doi.org/10.1007/s11082-022-04267-6
  7. R. Tintu, K. Saurav, K. Sulakshna, V. P. N. Nampoori, P. Radhakrishnan, and S. Thomas, J. Nano Oxide Glas., 2, No. 4: 167 (2010).
  8. A. H. Hadi and M. A. Habeeb, Journal of Mechanical Engineering Research and Developments, 44, No. 3: 265 (2021); https://jmerd.net/03-2021-265-274
  9. N. Hayder, M. A. Habeeb, and A. Hashim, Egyptian Journal of Chemistry, 63: 577 (2020); https://doi.org/10.21608/ejchem.2019.14646.1887
  10. S. M. Mahdi and M. A. Habeeb, Polymer Bulletin, 80, No. 12: 12741 (2023); https://doi.org/10.1007/s00289-023-04676-x
  11. M. A. Habeeb, A. Hashim, and N. Hayder, Egyptian Journal of Chemistry, 63: 709 (2020); https://doi.org/10.21608/ejchem.2019.13333.1832
  12. A. Hashim, M. A. Habeeb, and Q. M. Jebur, Egyptian Journal of Chemistry, 63: 735 (2020); https://doi.org/10.21608/ejchem.2019.14849.1901
  13. S. M. Mahdi and M. A. Habeeb, Physics and Chemistry of Solid State, 23, No. 4: 785 (2022); https://doi.org/10.15330/pcss.23.4.785-792
  14. N. K. Al-Sharifi and M. A. Habeeb, Silicon, 15: 4979 (2023); https://doi.org/10.1007/s12633-023-02418-2
  15. M. A. Habeeb and W. S. Mahdi, International Journal of Emerging Trends in Engineering Research, 7, No. 9: 247 (2019); https://doi.org/10.30534/ijeter/2019/06792019
  16. D. A. Sabur, A. Hashim, and M. A. Habeeb, Optical and Quantum Electronics, 55, Iss. 5: 457 (2023); https://doi.org/10.1007/s11082-023-04726-8
  17. A. Hashim, A. J. Kadham Algidsawi, H. Ahmed, A. Hadi, and M. A. Habeeb, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 2: 353 (2021); https://doi.org/10.15407/nnn.19.02.353
  18. M. A. Habeeb, A. Hashim, and N. Hayder, Egyptian Journal of Chemistry, 63: 697 (2020); https://doi.org/10.21608/ejchem.2019.12439.1774
  19. M. A. Habeeb and W. K. Kadhim, Journal of Engineering and Applied Sciences, 9, No. 4: 109 (2014); https://doi.org/10.36478/jeasci.2014.109.113
  20. A. A. Mohammed and M. A. Habeeb, Silicon, 15: 5163 (2023); https://doi.org/10.1007/s12633-023-02426-2
  21. M. A. Habeeb, Journal of Engineering and Applied Sciences, 9, No. 4: 102 (2014); https://doi.org/10.36478/jeasci.2014.102.108
  22. A. Hashim, A. J. Kadham, A. Hadi, and M. A. Habeeb, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 2: 327 (2021); https://doi.org/10.15407/nnn.19.02.327
  23. S. M. Mahdi and M. A. Habeeb, Digest Journal of Nanomaterials and Biostructures, 17, No. 3: 941 (2022); https://doi.org/10.15251/DJNB.2022.173.941
  24. A. Hashim, A. J. Kadham Algidsawi, H. Ahmed, A. Hadi, and M. A. Habeeb, Nanosistemi, Nanomateriali, Nanotehnologii, 19, Iss. 1: 91 (2021); https://doi.org/10.15407/nnn.19.01.091
  25. A. H. Hadi and M. A. Habeeb, Journal of Physics: Conference Series, 1973, No. 1: 012063 (2021); https://doi.org/10.1088/1742-6596/1973/1/012063
  26. Q. M. Jebur, A. Hashim, and M. A. Habeeb, Egyptian Journal of Chemistry, 63, No. 2: 611 (2020); https://doi.org/10.21608/ejchem.2019.10197.1669
  27. M. A. Habeeb and A. H. Mohammed, Optical and Quantum Electronics, 55, Iss. 9: 791 (2023); https://doi.org/10.1007/s11082-023-05061-8
  28. M. H. Dwech, M. A. Habeeb, and A. H. Mohammed, Ukr. J. Phys., 67, No. 10: 757 (2022); https://doi.org/10.15407/ujpe67.10.757
  29. R. S. Abdul Hamza and M. A. Habeeb, Optical and Quantum Electronics, 55, Iss. 8: 705 (2023); https://doi.org/10.1007/s11082-023-04995-3
  30. A. J. Kadham Algidsawi, A. Hashim, A. Hadi, M. A. Habeeb, and H. H. Abed, Physics and Chemistry of Solid State, 23, No. 2: 353 (2022); https://doi.org/10.15330/pcss.23.2.353-360
  31. M. A. Habeeb and W. H. Rahdi, Optical and Quantum Electronics, 55, Iss. 4: 334 (2023); https://doi.org/10.1007/s11082-023-04639-6
  32. H. Chandrakala, B. Ramaraj, and G. Madhu, Journal of Alloys and Compounds, 551: 531 (2013); https://doi.org/10.1016/j.jallcom.2012.10.188
  33. A. Hashim and M. A. Habeeb, Journal of Bionanoscience, 12, No. 5: 660 (2018); https://doi.org/10.1166/jbns.2018.1578
  34. S. M. Mahdi and M. A. Habeeb, AIMS Materials Science, 10, No. 2: 288 (2023); https://doi.org/10.3934/matersci.2023015
  35. O. E. Gouda, S. F. Mahmoud, A. A. El-Gendy, and A. S. Haiba, Indonesian Journal of Electrical Engineering, 12, No. 12: 7987 (2014); https://doi.org/10.11591/telkomnika.v12i12.6675
  36. A. A. Mohammed and M. A. Habeeb, East European Journal of Physics, 2: 157 (2023); https://doi.org/10.26565/2312-4334-2023-2-15
  37. N. K. Al-Sharifi and M. A. Habeeb, East European Journal of Physics, 2: 341 (2023); https://doi.org/10.26565/2312-4334-2023-2-40
  38. N. Tran, A. Mir, D. Mallik, A. Sinha, S. Nayar, and T. J. Webster, Int. J. Nanomedicine, 5: 277 (2010).
  39. Z. S. Jaber, M. A. Habeeb, and W. H. Radi, East European Journal of Physics, 2: 228 (2023); https://doi.org/10.26565/2312-4334-2023-2-25
  40. M. A. Habeeb and R. S. A. Hamza, Indonesian Journal of Electrical Engineering and Informatics, 6, No. 4: 428 (2018); https://doi.org/10.11591/ijeei.v6i1.511
  41. M. A. Habeeb and R. S. Abdul Hamza, Journal of Bionanoscience, 12, No. 3: 328 (2018); https://doi.org/10.1166/jbns.2018.1535
  42. Madalina Elena Grigore, Elena Ramona Biscu, Alina Maria Holban, Monica Cartelle Gestal, and Alexandru Mihai Grumezescu, Pharmaceuticals, 9, No. 4: 75 (2016); https://doi.org/10.3390/ph9040075
  43. A. J. K. Algidsawi, A. Hashim, A. Hadi, and M. A. Habeeb, Semiconductor Physics, Quantum Electronics and Optoelectronics, 24, No. 4: 472 (2021); https://doi.org/10.15407/spqeo24.04.472