Collection of scientific works Nanosystems, nanomaterials, nanotechnologies
Year 2025 Volume 23, Issue 3
Download the full version of the article (PDF) Open Access

B. B. KOLUPAYEV1, B. S. KOLUPAYEV2, V. V. LEVCHUK2, and I. S. VOITOVICH2

1Institute of Cybernetics, Stepan Demyanchuk International University of Economics and Humanities, 4s, Demianchuk Str., UA-33028 Rivne, Ukraine
2Rivne State University of Humanities, 31, Plastova Str., UA-33028 Rivne, Ukraine

Coordination Bonds as Information Systems of Polyvinyl Chloride–Nanodispersed Copper in an Ultrasonic Field

867–878 (2025)

PACS numbers: 62.23.Pq, 62.25.Fg, 62.80.+f, 81.07.Pr, 82.35.Lr, 82.35.Np, 83.60.-a

Received 20 September, 2024

Using computational methods, the influence of the donor–acceptor interplay between the structural elements of polyvinyl chloride (PVC) and nanodispersed Cu-filler (at 298 K≤T≤Tg−10 K, 0≤φ≤0.30 vol.% Cu, ω=0.4 MHz) on the change in the values of dynamic moduli (E, K, G), viscosity (μ), internal friction (tg δ), and relaxation times (τі) of the system. Based on the Maxwell–Frenkel model, the ways to regulate the behaviour of PVC composite in the ultrasonic and thermal fields are indicated.

KEY WORDS: nanosystems, coordination bonds, structural element, dissipation

DOI: https://doi.org/10.15407/nnn.23.03.0867

Citation:
B. B. Kolupayev, B. S. Kolupayev, V. V. Levchuk, and I. S. Voitovich, Coordination Bonds as Information Systems of Polyvinyl Chloride–Nanodispersed Copper in an Ultrasonic Field, Nanosistemi, Nanomateriali, Nanotehnologii, 23, No. 3: 867–878 (2025); https://doi.org/10.15407/nnn.23.03.0867
REFERENCES
  1. B. B. Kolupaev, J. Eng. Phys. Thermophys., 84: 1421 (2011); https://doi.org/10.1007/s10891-011-0613-6
  2. L. A. Bulavin, Physics of Polymers (Kyiv: VCP KNU Taras Shevchenko National University of Kyiv–National Academy of Sciences of Ukraine, 2004).
  3. B. B. Kolupaev, B. S. Kolupaev, and E. V. Lebedev, Physics of Condensed High Molecular Weight Systems, 10: 85 (2004).
  4. B. B. Kolupaev, V. V. Klepko, E. V. Lebedev, V. V. Levchuk, Yu. R. Maksimtsev, and B. S. Kolupaev, Polym. Sci. Ser. A, 57: 139 (2015); https://doi.org/10.1134/S0965545X15020078
  5. V. V. Nyzhnyk and T. Y. Nyzhnyk, Physical Chemistry of Polymers (Kyiv: Phytosociocentre, 2009).
  6. S. Y. Frenkel, I. M. Tsigelny, and B. S. Kolupaev, Мolecular Cybernetics (Lviv: Svit, 1990) (in Russian).
  7. V. V. Klepko, B. B. Kolupaev, B. S. Kolupaev, and E. V. Lebedev, Polym. Sci. Ser. B, 49: 18 (2007); https://doi.org/10.1134/S1560090407010058
  8. D. W. Van Krevelen and K. Nijenhuis, Properties of Polymers (Amsterdam: Elsevier, 2009).
  9. P. H. C. Camargo, K. G. Satyanarayana, and F. Wypych, Materials Research, 12: 1 (2009); https://dx.doi.org/10.1590/S1516-14392009000100002
  10. F. Candau and R. H. Ottewill, An Introduction to Polymer Colloids (Dordrecht: Springer, 2012).
  11. B. S. Kolupaev, Relaxation and Thermal Properties of Polymers (Lviv: Vyshcha Shkola, 1980) (in Russian).
  12. S. Hunklinger and C. Enss, Solid State Physics (Berlin–Boston: De Gruyter, 2022); https://doi.org/10.1515/9783110666502
  13. B. B. Kolupaev, B. S. Kolupaev, V. V. Levchuk, B. D. Nechyporuk, Yu. R. Maksimtsev, and V. A. Sidletskii, Mech. Compos. Mater., 54: 333 (2018); https://doi.org/10.1007/s11029-018-9743-7
  14. L. A. Bulavin, Y. F. Zabashta, and O. S. Svechnikova, Ukr. J. Phys., 44(6): 791 (1999) (in Ukrainian).